Nickel(II) hydroxide
Names
IUPAC name
Other names
Nickel hydroxide, Theophrastite
Identifiers
  • 12054-48-7
  • 36897-37-7 (monohydrate)
ChemSpider
ECHA InfoCard100.031.813
EC Number
  • 235-008-5
RTECS number
CompTox Dashboard(EPA)
  • Key: BFDHFSHZJLFAMC-UHFFFAOYSA-L
  • Key: BFDHFSHZJLFAMC-NUQVWONBAJ
  • [Ni+2].[OH-].[OH-]
Properties
Ni(OH)2
Molar mass92.724 g/mol (anhydrous)
110.72 g/mol (monohydrate)
Appearancegreen crystals
Density4.10 g/cm3
Melting point 230 °C (446 °F; 503 K) (anhydrous, decomposes)
0.13 g/L
+4500.0·10−6 cm3/mol
Structure[1]
hexagonal, hP3
P3m1, No. 164
α = 90°, β = 90°, γ = 120°
Thermochemistry
79 J·mol−1·K−1[2]
Std enthalpy of
formationfH298)
−538 kJ·mol−1[2]
Hazards
Safety data sheetExternal SDS
GHS pictograms[3]
GHS Signal wordDanger[3]
H302, H332, H315, H334, H317, H341, H350, H360, H372[3]
P260, P284, P201, P280, P405, P501[3]
Lethal dose or concentration (LD, LC):
1515 mg/kg (oral, rat)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references
  1. Ni Dmg 2 2 Aq Name Generator
  2. Calculator

Ni Dmg 2 2 Aq Name Generator

The test tube in the middle contains a precipitate of nickel(II) hydroxide

Calculator

Its abbreviation is dmgH 2 for neutral form, and dmgH for anionic form, where H stands for hydrogen. This colourless solid is the dioxime derivative of the diketone butane-2,3-dione (also known as diacetyl). DmgH 2 is used in the analysis of palladium or nickel. Its coordination complexes are of theoretical interest as models for enzymes and as. The reaction with ethylenediamine gives: Ni(en)32+(aq) The reaction with NaOH gives: Ni(OH)2(s) The reaction with EDTA gives: NiEDTA2+(aq) Write a balanced equation for each reaction. How many d electrons are there in Ni2+? For each complex ion formed, indicate the coordination number of the copper atom. Name each complex. Balance Chemical Equation - Online Balancer Balance Chemical Equation - Online Balancer. 0 NiSO 4 + 0 DMG + NH 3 = -0 Ni(DMG) 2 + 0 (NH 4) 2 SO 4 + NH 3 Warning: some compounds do not play role in the reaction and have 0 coeficients. Always use the upper case for the first character in the element name and the lower case for the second.

NICKEL (II) The reaction with DMG gives: Ni(DMG)212 (aq) The reaction with HCl gives: NiClg(aq) The reaction with ethylenediamine gives: Ni(en)al2(aq) The reaction with NaOH gives: Ni(OH)2(s) The reaction with EDTA gives: NIEDTA2(ag) Write a balanced equation for each reaction. Indicate the coordination number of the copper atom. Continuing on with the analysis of the Ni-en complex as found in question #3, 40 mL of dimethylglyoxime, DMG, solution was added to the titrated nickel-en complex solution. The resulting beautiful red complex, Ni(DMG)2 was collected by filtration and found to weigh 0.443 g. What is the mass (in grams) of Ni in the Ni-en complex analyzed? Jul 07, 2009 Ni2+(aq) + 2DMG-Ni(DMG)2(s) The red Ni(DMG)2 is neutral and there are no ion-dipole interactions with H2O molecules so the cmplx is highly insoluble and hence the top equilibrium is tipped to the right until the rxn is complete. This rxn was used for decades for the gravimetric determination of Ni (I did it as an undergraduate!).

Nickel(II) hydroxide is the inorganic compound with the formula Ni(OH)2. It is an apple-green solid that dissolves with decomposition in ammonia and amines and is attacked by acids. It is electroactive, being converted to the Ni(III) oxy-hydroxide, leading to widespread applications in rechargeable batteries.[4]

Properties[edit]

Nickel(II) hydroxide has two well-characterized polymorphs, α and β. The α structure consists of Ni(OH)2 layers with intercalated anions or water.[5][6] The β form adopts a hexagonal close-packed structure of Ni2+ and OH ions.[5][6] In the presence of water, the α polymorph typically recrystallizes to the β form.[5][7] In addition to the α and β polymorphs, several γ nickel hydroxides have been described, distinguished by crystal structures with much larger inter-sheet distances.[5]

The mineral form of Ni(OH)2, theophrastite, was first identified in the Vermion region of northern Greece, in 1980. It is found naturally as a translucent emerald-green crystal formed in thin sheets near the boundaries of idocrase or chlorite crystals.[8] A nickel-magnesium variant of the mineral, (Ni,Mg)(OH)2 had been previously discovered at Hagdale on the island of Unst in Scotland.[9]

Reactions[edit]

Nickel(II) hydroxide is frequently used in electrical car batteries.[6] Specifically, Ni(OH)2 readily oxidizes to nickel oxyhydroxide, NiOOH, in combination with a reduction reaction, often of a metal hydride (reaction 1 and 2).[10]

Reaction 1 Ni(OH)2 + OH → NiO(OH) + H2O + e

Reaction 2 M + H2O + e → MH + OH

Net Reaction (in H2O)Ni(OH)2 + M → NiOOH + MH

Of the two polymorphs, α-Ni(OH)2 has a higher theoretical capacity and thus is generally considered to be preferable in electrochemical applications. However, it transforms to β-Ni(OH)2 in alkaline solutions, leading to many investigations into the possibility of stabilized α-Ni(OH)2 electrodes for industrial applications.[7]

If i only boss and never train should i be stacking boss% over atk%? I read that your damage output with atk% scales better if you have a lot. Right now i have 356% boss dmg (w. Noblesse skill) 93% pdr (buffed) and 66% atk. I am able to swap my weapon (i have two) to get 286% boss, 96% PDR, 84% atk. May 31, 2015  Mostly about 9Dragons and a few other games I play from time to time. Hope your enjoy and comment as you wish! 46 Followers, 76 Following, 1 Posts - See Instagram photos and videos from DaBoss (@dmgboss). How to dmg the 6f boss lm3. In my graphs you would see the comparison of 30% Boss Dmg vs 9% Atk and 40% Boss Dmg vs%12 Atk, the more negative (blue) a certain point is the more%Boss Dmg would increase your range against bosses, while the more postive (yellow) a certain point is the more%Atk would increase your range against bosses.%Stat vs%Crit Damage (Gloves). Boss LM-2B: This is an older version of the well-known LMB-3.For a long time I didn't bother reviewing it because on the surface it just looks like it would be the same as an LMB-3 but without the Ratio knob-and I happen to think the Ratio knob is a very important feature.

Synthesis[edit]

The synthesis entails treating aqueous solutions of nickel(II) salts with potassium hydroxide.[11]

Toxicity[edit]

The Ni2+ ion is a known carcinogen. Toxicity and related safety concerns have driven research into increasing the energy density of Ni(OH)2 electrodes, such as the addition of calcium or cobalt hydroxides.[4]

See also[edit]

References[edit]

  1. ^Enoki, Toshiaki; Tsujikawa, Ikuji (1975). 'Magnetic Behaviours of a Random Magnet, NipMg(1-p)(OH2)'. Journal of the Physical Society of Japan. 39 (2): 317. doi:10.1143/JPSJ.39.317.
  2. ^ abZumdahl, Steven S. (2009). Chemical Principles 6th Ed. Houghton Mifflin Company. p. A22. ISBN978-0-618-94690-7.
  3. ^ abcd'Nickel Hydroxide'. American Elements. Retrieved 2018-08-30.
  4. ^ abChen, J.; Bradhurst, D.H.; Dou, S.X.; Liu, H.K. (1999). 'Nickel Hydroxide as an Active Material for the Positive Electrode in Rechargeable Alkaline Batteries'. J. Electrochem. Soc. 146 (10): 3606–3612. doi:10.1149/1.1392522.
  5. ^ abcdOliva, P.; Leonardi, J.; Laurent, J.F. (1982). 'Review of the structure and the electrochemistry of nickel hydroxides and oxy-hydroxides'. Journal of Power Sources. 8 (2): 229–255. doi:10.1016/0378-7753(82)80057-8.
  6. ^ abcJeevanandam, P.; Koltypin, Y.; Gedanken, A. (2001). 'Synthesis of Nanosized α-Nickel Hydroxide by a Sonochemical Method'. Nano Letters. 1 (5): 263–266. doi:10.1021/nl010003p.
  7. ^ abShukla, A.K.; Kumar, V.G.; Munichandriah, N. (1994). 'Stabilized α-Ni(OH)2 as Electrode Material for Alkaline Secondary Cells'. J. Electrochem. Soc. 141 (11): 2956–2959. doi:10.1149/1.2059264.
  8. ^Marcopoulos, T.; Economou, M. (1980). 'Theophrastite, Ni(OH)2, a new mineral from northern Greece'(PDF). American Mineralogist. 66: 1020–1021.
  9. ^Livingston, A.; Bish, D. L. (1982). 'On the new mineral theophrastite, a nickel hydroxide, from Unst, Shetland, Scotland'(PDF). Mineralogical Magazine. 46 (338): 1. doi:10.1180/minmag.1982.046.338.01.
  10. ^Ovshinsky, S.R.; Fetcenko, M.A.; Ross, J. (1993). 'A nickel metal hydride battery for electric vehicles'. Science. 260 (5105): 176–181. doi:10.1126/science.260.5105.176. PMID17807176.
  11. ^Glemser, O. (1963) 'Nickel(II) Hydroxide' in 'Handbook of Preparative Inorganic Chemistry, 2nd ed. G. Brauer (ed.), Academic Press, NY. Vol. 1. p. 1549.

External links[edit]

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